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Determination of Organic and Reduced Inorganic Sulfur by Multi-element Scanning Thermal Analysis

Biology Group    Start Submission

Yuch-Ping Hsieh* and Glynnis C Bugna

Volume4-Issue7
Dates: Received: 2023-07-20 | Accepted: 2023-07-31 | Published: 2023-07-31
Pages: 1156-1165

Abstract

Determination of organic sulfur in solid environmental samples has been difficult because there is no appropriate separation technology. Routine organic sulfur analysis has mostly been done indirectly by the difference between the total and the inorganic sulfur contents. This indirect analysis is tedious, accumulating multiple sampling and procedural errors, and has no chemical characterization information. There are modern technologies such as S-XANES for direct sulfur analysis on solid samples. But they are sophisticated, expensive, and unavailable for routine sulfur analysis. Due to those analytical difficulties, our understanding of sulfur chemistry in solid samples has been limited. This study was initiated to apply a convenient Multi-Element Scanning Thermal Analysis (MESTA) method for direct analysis of organic and reduced inorganic sulfur in solid samples. If successful, sulfur MESTA will be a convenient and powerful tool for studying environmental sulfur cycles and sulfur-containing materials. We used 27 reference organic and reduced inorganic sulfur compounds to validate the MESTA method. The results indicate that MESTA can directly quantify and characterize organic and reduced inorganic sulfur compounds. Recoveries of the reference compounds were in the range of 77.0% to 97.7% except for sulfate functional group containing compounds of bathophenanthrolinedisulfonic acid (57.4 ± 6.7%), sodium thiosulfate (60.6 ± 3.1%) and sodium dodecyl sulfate (38.0 ± 2.6%). MESTA is rapid, sensitive, and inexpensive. It is a convenient and powerful tool for sulfur analysis in a wide range of solid, liquid, or mixed samples.

FullText HTML FullText PDF DOI: 10.37871/jbres1781


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Copyright

© 2023 Yuch-Ping H, et al. Distributed under Creative Commons CC-BY 4.0

How to cite this article

Yuch-Ping H, Bugna GC. Determination of Organic and Reduced Inorganic Sulfur by Multi-element Scanning Thermal Analysis. 2023 July 31; 4(7): 1156-1165. doi: 10.37871/jbres1781, Article ID: JBRES1781, Available at: https://www.jelsciences. com/articles/jbres1781.pdf


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References


  1. Trudinger PA, Chemistry of the sulfur cycle. In: Tabatabai MA, editor. Sulfur in Agriculture, Agron Monogr. 27, ASA, CSSA, SSSA, Wisconsin; 1986. p.1-22.
  2. Schlesinger W, Bernhardt E. Biogeochemistry: An analysis of global change. 3rd ed. San Diego: Academic Press; 2013.
  3. Freney FR. Forms and reactions of organic sulfur compounds in soils. In: Tabatabai MA, editor. Sulfur in Agriculture, Agron Monogr. 27, ASA, CSSA, SSSA, Wisconsin; 1986. p.207-232.
  4. Blanchar RW. Measurements of sulfur in soils and plants. In: Tabatabai MA, editor. Sulfur in Agriculture, Agron Monogr. 27, ASA, CSSA, SSSA, Wisconsin; 1986. p.455-490.
  5. Kelemen SR, Afeworki M, Gorbaty ML, Sansone M, Kwiatek PJ, Walters CC, Freund H, Siskin M, Bence AE, Curry DJ, Solum M, Pugmire RJ, Vandenbroucke M, Leblond M, Behar F. Direct characterization of kerogen by x-ray and solid-state C-13 nuclear magnetic resonance methods. Energy Fuels. 2007;21:1548-1561. doi: 10.1021/ef060321h.
  6. Prietzel J, Thieme J, Tyufekchieva N, Paterson D, McNulty I, Kögel-Knabner I. Sulfur speciation in well-aerated and wetland soils in a forested catchment assessed by sulfur K-edge X-ray Absorption Near-Edge Spectroscopy (XANES). J Plant Nutr Soil Sci. 2009;172:393-409. doi: 10.1002/jpln.200800054.
  7. Manceau, Nagy K. Quantitative analysis of sulfur functional groups in natural organic matter by XANES spectroscopy. Geochim Cosmochim Acta. 2012;99:206-223. doi: 10.1016/j.gca.2012.09.033.
  8. Bolin TB, Birdwell JE, Lewan MD, Hill RJ, Grayson MB, Mitra-Kirtley S, Bake KD, Craddock PR, Abdallah W, Pomerantz AE. Sulfur species in source rock bitumen before and after hydrous pyrolysis determined by X‑ray absorption near-edge structure. Energy Fuels. 2016;30:6264-6270. doi: 10.1021/acs.energyfuels.6b00744.
  9. Marguí E, Resano M, Queralt I. A sustainable and simple energy dispersive X-ray fluorescence method for sulfur determination at trace levels in biodiesel samples via formation of biodiesel spots on a suitable solid support. Spectrochim Acta B. 2019;156:7-12. doi: 10.1016/j.sab.2019.04.003.
  10. Liu L, Song C, Tian S, Zhang Q, Cai X, Liu Y, Liu Z, Wang W. Structural characterization of sulfur-containing aromatic compounds in heavy oils by FT-ICR mass spectrometry with a narrow isolation window. Fuel. 2019;240:40-48. doi: 10.1016/j.fuel.2018.11.130.
  11. Hsieh YP. A novel Multielemental Scanning Thermal Analysis (MESTA) method for the identification and characterization of solid substances. J AOAC Int. 2007 Jan-Feb;90(1):54-9. PMID: 17373436.
  12. Hsieh YP, Bugna GC. Analysis of black carbon in sediments and soils using Multi-Element Scanning Thermal Analysis (MESTA). Org Geochem. 2008;39:1562-1571. doi: 10.1016/j.orggeochem.2008.07.015.
  13. Hsieh YP, Bugna G, Robertson K. Thermochemical properties of PM2.5 as indicator of combustion phase of fires. Atmosphere. 2018;9:230-243. doi: 10.3390/atmos9060230.
  14. Hsieh YP, Bugna GC, Robertson KM. Examination of two assumptions commonly used to determine PM2.5 emission factors for wild fires. Atmos Environ. 2016;147:274-283. doi: 10.1016/j.atmosenv.2016.10.012.


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