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Review of Materials Science and Technological Applications of a Unique Transformational Multifunctional Ultrananocrystalline Diamond (UNCD) Coating

Journal of Biomedical Research & Environmental Sciences article abstract with citation details, DOI, publication dates, subject areas, full text links, and references.

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Open Access
Article Type Review Article
Subject General Science
OCLC JBRES Record
Orlando Auciello*
Issue: Volume5-Issue10
Pages: 1291-1304
Received: 2024-09-16
Accepted: 2024-10-10
Published: 2024-10-15

Abstract

Microcrystalline Diamond (MCD) (grains ≥ 1 µm) and Nanocrystalline Diamond (NCD) (grains 20-900 nm) coatings have been grown using Microwave Plasma Chemical Vapor Deposition (MPCVD), exciting H2/CH4 gas, via microwave power, in evacuated chambers, producing C atoms, bonding on surfaces with sp3 C atoms diamond bonds. Alternatively, MCD/NCD films have been grown via Hot Filament Chemical Vapor Deposition (HFCVD), using ~2200°C hot filaments, cracking CH4 into C atoms. Auciello-Gruen-Krauss developed (1990s) a transformational MPCVD process, growing unique multifunctional Ultrananocrystalline Diamond (UNCDTM) coating (3-5 nm grains), using patented Ar/CH4 gas mixture. Subsequently, Auciello’s group developed HFCVD process with Ar/CH4/H2 and H2/CH4. Gases flowing though filaments heated to ~2300°C. UNCD coatings exhibit unique multifunctionalities, enabling new industrial/high-tech/medical products, namely: 1) UNCD-coated pump seals/bearings/AFM tips (marketed worldwide since 2009); 2) unique electrically conductive Nitrogen atoms-grain boundary incorporated N-UNCD-coating on commercial graphite / copper anodes anodes, enabling superior stable capacity energy/safer Li-ion batteries; 3) Unique water corrosion resistant/electrically conductive Boron-doped B-UNCD-coated metal electrodes, purifying water, via viruses/pathogens’ killing by Ozone (O3) molecules generation.; 4) Best biocompatible UNCD coating (made of C atoms in human DNA/cells life’s elements) enable new medical products (e.g., UNCD-coated Si-microchip implanted on retina, to restore partial vision to blind people; UNCD-coated Dental Implants (DI), eliminating oral fluids corrosion of metal-DIs (clinical trials in progress),; 5) UNCD-coated magnet, outside eye, attracts injected biocompatible superparamagnetic nanoparticles, reattaching retina on eye’s wall; 6) superhydrophobic UNCD coated polymer-valves, drain inner eyes’ fluid of people with glaucoma, inhibiting blindness.

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© 2024 Auciello O. Distributed under Creative Commons CC-BY 4.0 Creative CommonsAttribution

How to cite this article

Auciello O. Review of Materials Science and Technological Applications of a Unique Transformational Multifunctional Ultrananocrystalline Diamond (UNCD) Coating. J Biomed Res Environ Sci. 2024 Oct 15; 5(10): 1291-1304. doi: 10.37871/ jbres2017, Article ID: JBRES2017, Available at: https://www.jelsciences.com/articles/jbres2017.pdf

Subject area(s)

Material Science

References

  1. Spitsyn BV, Bouilov LL, Derjaguin BV. Vapor growth of diamond on diamond and other surfaces. J Cryst Growth. 1981;52:219-226. doi: 10.1016/0022-0248(81)90197-4.
  2. Matsumoto S, Sato Y, Tsutsumi M, Setaka N. Growth of diamond particles from methane-hydrogen gas. J Mater Sci. 1982;17:3106-3112. doi: 10.1007/BF01203472.
  3. Matsumoto S. Development of CVD diamond synthesis techniques. Proc. of 1st symposium on diamond and diamond-like films. Electrochem Soc Proc. 1989;50:89.
  4. Hirose Y, Kondo N. Program and book of abstracts. Japan Appl Phys Spring Meeting Proceedings. 1988.
  5. Kamo M. Sato Y, Matsumoto S, Setaka N. Diamond synthesis from gas phase in microwave plasma. J Cryst Growth.1983;62(3):642-644. doi: 10.1016/0022-0248(83)90411-6.
  6. Matsumoto S., Chemical vapor deposition of diamond in RF glow discharge, J. Mater. Sci. Lett., 1985, 4(5), 600-602.
  7. Dischler B., Wild C., Low-pressure synthetic diamond: Manufacturing and applications. Heidelberg. Springer. 1998.
  8. Bachmann PK, Hagemann HJ, Lade H, Leers D, Weichert DUH. Wilson H, Fournier D, Plamann K. Thermal properties of C/H, C/H/O, C/H/N and C/H/X grown polycrystalline CVD diamond. Diamond and Related Materials. 1995;4:820-826. doi: 10.1016/0925-9635(94)05229-8.
  9. Sharda T, Bhattacharyya S. Advances in nanocrystalline diamond. In: Nalwa HS, editor. Encyclopedia of Nanoscience and Nanotechnology. California: American Scientific Publishers; 2004.
  10. Butler J.E., Sumant A.V., The CVD of nanodiamond materials, Chem. Vapor Deposition, 2008, 14, 145-160.
  11. Auciello O, Sumant AV. Status review of the science and technology of ultrananocrystalline diamond (UNCDTM) films and application to multifunctional devices. Diamond and Related Materials. 2010;19:699-718. doi: 10.1016/j.diamond.2010.03.015.
  12. Sumant AV, Auciello O, Liao M, Williams OA. MEMS/NEMS Based on Mono, Nano, and Ultrananocrystalline Diamond Films. MRS Bulletin. 2014:39(6):511-516. doi: 10.1557/mrs.2014.98.
  13. Rotter S. Proceedings of the applied diamond conference/frontier carbon technologies ADC/FCT '99. Yoshikawa M, Koga YCP, Miyoshi K, editors. Tokyo; 1999.
  14. Kohn E, Gluche P, Adamschik M. Diamond MEMS-a new emerging technology. Diamond and Related Materials. 1999;8:934-940. doi: 10.1016/S0925-9635(98)00294-5.
  15. Sumant AV, Gilbert PUPA, Grierson DS, Konicek AR, Abrecht M, Butler JE, Feygelson T, Rotter SS, Carpick RW, Surface composition, bonding, and morphology in the nucleation and growth of ultra-thin, high quality nanocrystalline diamond films. Diamond and Related Materials. 2007;16(4-7):718-724. doi: 10.1016/j.diamond.2006.12.011.
  16. Smalley RE. Discovering the fullerenes. Rev Mod Phys. 1997.
  17. Gruen DM. Nanocrystalline diamond films. Annual Review of Materials Science. 1999;29:211-259. doi: 10.1146/annurev.matsci.29.1.211.
  18. Naguib N, Birrell J, Elam JA, Carlisle JA, Auciello O. A method to grow carbon thin films consisting entirely of diamond grains 3-5 nm in size and high-energy grain boundaries. US Patent #7,128,8893. 2006.
  19. May PW, Harvey JN, Smith JA, Mankelevich YA, Re-evaluation of the mechanism for ultrananocrystalline diamond deposition from Ar∕CH4∕H2 gas mixtures. J Appl Phys. 2006;99:104907. doi: 10.1063/1.2195347.
  20. Xiao X, Birrell J, Gerbi JE, Auciello O, Carlisle JA. Low temperature growth of ultrananocrystalline diamond. J Appl Phys. 2004;96:2232-2239. doi: 10.1063/1.1769609.
  21. Carlisle JA, Gruen DM, Auciello O, Xiao X. A method to grow pure nanocrystalline diamond films at low temperatures and high deposition rates. US Patent # 7,556,982. 2009.
  22. Schwarz S, Rosiwal SM, Frank M, Breidt D, Singer RF. Dependence of the growth rate, quality, and morphology of diamond coatings on the pressure during the CVD-process in an industrial hot-filament plant. Diamond Related Materials. 2002;11:589-595. doi: 10.1016/S0925-9635(01)00702-6.
  23. Hao T, Zhang H, Shi C, Han G, Nano-crystalline diamond films synthesized at low temperature and low pressure by hot filament chemical vapor deposition. Surf Coat Tech. 2006;201:801-806. doi: 10.1016/j.surfcoat.2005.12.037.
  24. Liang X, Wang L, Zhu H, Yang D. Effect of pressure on nanocrystalline diamond films deposition by hot filament CVD technique from CH4/H2 gas mixture. Surf Coat Tech. 2007;202:261-267. doi: 10.1016/j.surfcoat.2007.05.032.
  25. May PW, Smith JA, Mankelevich YA. Deposition of NCD films using hot filament CVD and Ar/ CH4/H2 gas mixtures. Diamond Related Materials. 2006;15:345-352. doi: 10.1016/j.diamond.2005.06.044.
  26. Lin T, Yu GY, Wee ATS, Shen ZX. Compositional mapping of the argon–methane–hydrogen system for polycrystalline to nanocrystalline diamond film growth in a hot-filament chemical vapor deposition system. Appl Phys Lett. 2006;77:2692-2694. doi: 10.1063/1.1320039.
  27. Fuentes-Fernandez EMA, Alcantar-Peña JJ, Lee G, Boulom A, Phan H, Smith B, Nguyen T, Sahoo S, Ruiz-Zepeda F, Arellano-Jimenez MJ, Gurman P, Martinez-Pere CA, Yacaman MJ, Katiyar RS, Auciello O. Synthesis and characterization of microcrystalline diamond to ultrananocrystalline diamond films via hot filament chemical vapor deposition for scaling to large area applications. Thin Solid Films. 2016;603:62-68. doi: 10.1016/j.tsf.2015.11.088.
  28. Alcantar-Peña JJ, Lee G, Fuentes-Fernandez EMA, Gurman P, Quevedo-Lopez M, Sahoo S, Katiyar RS, Berman D, Auciello O. Science and technology of diamond films grown on HfO2 interface layer for transformational technologies. Diamond and Related Materials. 2016;69:221-228. doi: 10.1016/j.diamond.2016.09.010.
  29. Alcantar-Peña JJ, Montes J, Arellano-Jimenez MJ, Ortega Aguilar JE, Berman-Mendoza D, García R, Yacaman MJ, Auciello O. Low temperature hot filament chemical vapor deposition of ultrananocrystalline diamond films with tunable sheet resistance for electronic power devices. Diamond and Related Materials. 2016;69:207-213. doi: 10.1016/j.diamond.2016.09.010.
  30. Alcantar-Peña JJ, de Obaldia E, Montes-Gutierrez EJ, Kang K, Arellano-Jimenez MJ, Ortega Aguilar JE, Suchy GP, Berman-Mendoza D, Garcia R, Yacaman MJ, Auciello O. Fundamentals towards large area synthesis of multifunctional ultrananocrystalline diamond films via large area hot filament chemical vapor depal devices. Diamond and Related Materials. 2017;78:1-11. doi: 10.1016/j.diamond.2017.07.004.
  31. Auciello O, Alcantar-Peña JJ, de Obaldia E, Fundamentals on Synthesis and Properties of Ultrananocrystalline Diamond (UNCDTM) Coatings. In: Ultrananocrystalline diamond coatings for new generation high-tech and medical devices. Auciello O, editor. Cambridge Publisher; 2022. p.1-85. doi: 10.1017/9781316105177.002.
  32. Ferrari AC, Robertson J. Interpretation of raman spectra of disordered and amorphous carbon. Phys Rev B. 2000;61:14095-107. doi: 10.1103/PhysRevB.61.14095.
  33. Klauser F, Steinmüller-Nethl D, Kaindl R, Bertel E, Memmel N. raman studies of nano- and ultra-nanocrystalline diamond films grown by hot-filament CVD. Chem Vap Deposition. 2010;16:127-135. doi: 10.1002/cvde.200906827.
  34. Ding MQ, Krauss R, Auciello O, Gruen DM, Corrigan T, Kordesch ME, Temple D, Palmer D. McGuire G. Studies of field emission from bias-grown diamond thin films. J Vac Sci Tech B. 1999;17:705-709. doi: 10.1116/1.590623.
  35. Lee YC, Lin SJ, Chia CT, Cheng HF, Lin IN, Effect of processing parameters on the nucleation behavior of nano-crystalline diamond film. Diamond and Related Materials. 2005;14:296-301. doi: 10.1016/j.diamond.2004.10.015.
  36. Lee YC, Lin SJ, Lin CY, Yip MC, Fang W, Lin IN. Pre-nucleation techniques for enhancing nucleation density and adhesion of low temperature deposited ultra-nano-crystalline diamond. Diamond and Related Materials. 2006;15:2046-2050. doi: 10.1016/j.diamond.2006.09.007.
  37. Chen YC, Zhong XY, Konicek AR, Grierson DS, Tai NH, Lin IN, Kabius B, Hiller JM, Sumant AV, Carpick RW, Auciello O. Synthesis and characterization of smooth ultrananocrystalline diamond films via low pressure bias-enhanced nucleation and growth. Appl Phys Lett. 2008;92:133113. doi: 10.1063/1.2838303.
  38. Auciello O. Ultrananocrystalline Diamond (UNCD) films as hermetic/biocompatible/bioinert coating for encapsulation of eye implantable microchip to restore partial vision to blind people. In: Ultrananocrystalline diamond coatings for new generation high-tech and medical devices. Auciello O, editor. Cambridge Publisher; 2022. p.86-106. doi: 10.1017/9781316105177.003.
  39. Kang K, Auciello O, Olmedo DG, Tasat DR, López-Chávez G. Science and technology of biocompatible Ultrananocrystalline Diamond (UNCD™) coatings for a new generation of implantable prostheses: First application to dental implants and artificial hips. In: Ultrananocrystalline diamond coatings for new generation high-tech and medical devices. Auciello O, editor. Cambridge Publisher, 2022. p.141- 174. doi: 10.1017/9781316105177.006.
  40. Shi B, Auciello O. Science and technology of novel Ultrananocrystalline Diamond (UNCDTM) scaffolds for stem cells growth and differentiation for developmental biology and biological treatment of human medical conditions. In: Ultrananocrystalline Diamond Coatings for New Generation High-Tech and Medical Devices. Auciello O. editor, Cambridge Publisher; 2022. p.175-196.
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