Covid-19 Research

Open Access
Review Article
OCLC

Hydrogen Generation from the Reaction of Aluminum and Water Using Aluminum Hydroxide Synthesized from Different Salts Google Scholar

Read • Cite • Share — permanent Open Access hosting with DOI tracking

Pin-Yi Lu, Yung-Lun Fan, Kai-Yu Shih, Min-Han Lee and Hong-Wen Wang

Volume6-Issue12
Dates: Received: 2025-11-09 | Accepted: 2025-12-29 | Published: 2025-12-05
Pages: 1877-1884

Abstract

This study investigates hydrogen generation from the reaction of aluminum and water using aluminum hydroxide synthesized under different conditions as a catalyst. The catalysts were prepared using sodium aluminate, aluminum nitrate, aluminum chloride, graphite-assisted precipitation, and re-precipitation from inactive aluminum hydroxide. The effects of precursor salt, synthesis environment, and reactivation treatment on catalyst phase composition and hydrogen production efficiency were examined. Results indicate that sodium-aluminate-derived aluminum hydroxide produced the highest hydrogen generation efficiency, attributable to its distinct phase structure and surface properties.

FullText HTML FullText PDF DOI: 10.37871/jbres2235


Certificate of Publication




Copyright

© 2025 Pin-Yi L, et al. Distributed under Creative Commons CC-BY 4.0

How to cite this article

Pin-Yi L, Yung-Lun F, Kai-Yu S, Min-Han L, Hong-Wen W. Hydrogen Generation from the Reaction of Aluminum and Water Using Aluminum Hydroxide Synthesized from Different Salts. J Biomed Res Environ Sci. 2025 Dec 05; 6(12): 1877-1884. doi: 10.37871/jbres2235, Article ID: JBRES2235, Available at: https://www.jelsciences.com/articles/jbres2235.pdf


Subject area(s)

References


  1. Woodall JM. Hydrogen fuel generation from solid aluminum. US Patent. 2008.
  2. Woodall JM. Power generation from solid aluminum. US Patent. 2008.
  3. Parmuzina AV, Kravchenko OV. Activation of aluminum metal to evolve hydrogen from water. Int J Hydrogen Energy. 2008;33:3073-6. doi: 10.1016/j.ijhydene.2008.02.025.
  4. Czech E, Troczynski T. Hydrogen generation through massive corrosion of deformed aluminum in water. Int J Hydrogen Energy. 2010;35:1029-37. doi:10.1016/j.ijhydene.2009.11.085.
  5. Alinejad B, Mahmoodi K. A novel method for generating hydrogen by hydrolysis of highly activated aluminum nanoparticles in pure water. Int J Hydrogen Energy 2009;34:7934-8. doi:10.1016/j.ijhydene.2009.07.028.
  6. Chaklader A. Hydrogen generation from water split reaction. US Patent. 2002.
  7. Deng ZY, Liu YF, Tanaka Y, Ye JH, Sakka Y. Modification of Al particle surfaces by γ-Al2O3 and Its effect on the corrosion behavior of Al. J Am Ceram Soc. 2005;88:977-9. doi: 10.1111/j.1551-2916.2005.00154.x.
  8. Deng ZY, Liu YF, Tanaka Y, Zhang HW, Ye JH, Kagwa Y. Temperature effect on hydrogen generation by the reaction of α-Al2O3-modified Al powder with distilled water. J Am Ceram Soc. 2005;88:2975-77. doi: 10.1111/j.1551-2916.2005.00534.x.
  9. Deng ZY, Ferreira JMF, Tanaka Y, Ye JH. Physicochemical mechanism for the continuous reaction of α-Al2O3 modified aluminum powder with water. J Am Ceram Soc. 2007;90:1521-26. doi: 10.1111/j.1551-2916.2007.01546.x.
  10. Yang Y, Gai WZ, Deng ZY, Zhou JG. Hydrogen generation by the reaction of Al with water promoted by an ultrasonically prepared Al(OH)3 suspension. Int J Hydrogen Energy. 2014;39:18734-42. doi: 10.1016/j.ijhydene.2014.09.085.
  11. Gai WZ, Zhang SH, Yang Y, Deng ZY. High activity AlOOH catalyzed Al hydrolysis for hydrogen generation. Sustain Energy Technol. 2020;38:100-676. doi: 10.1016/j.seta.2020.100676.
  12. Gai WZ, Deng ZY. Enhanced hydrogen production from Al-water reaction: Strategies, performances, mechanisms and applications. Renewable Energy. 2024;226:120-397. doi: 10.1016/j.renene.2024.120397.
  13. Wang HW, Chung HW, Teng HT, Cao G. Generation of hydrogen from aluminum and water - Effect of metal oxide nanocrystals and water quality. Inter J Hydrogen Energy. 2011;36:15136-44. doi: 10.1016/j.ijhydene.2011.08.077.
  14. Teng HT, Lee TY, Chen YK, Wang HW, Cao G. Effect of Al(OH)3 on the Generation of Hydrogen from the Aluminum-Water System. J Power Sources. 2012;219:16-21 doi: 10.1016/j.jpowsour.2012.06.077.
  15. Chen YK, Teng HT, Lee TY, Wang HW. Rapid hydrogen generation from aluminum-water system by adjusting water ratio to various aluminum/aluminum hydroxide. Inter J Energy Environ Eng. 2014. doi: 10.1007/s40095-014-0087-3.
  16. Wang HW, Chin MS. Rapid hydrogen generation from aluminum-water system using synthesized aluminum hydroxide catalyst. Inter J Chem Eng Appl. 2015;6:146-51. doi: 10.7763/IJCEA.2015.V6.470.
  17. Wen YC, Huang WM, Wang HW. Kinetics study on the generation of hydrogen from an aluminum/water system using synthesized Al(OH)3. Inter J Energy Research. 2018; 42:1615-24. doi: 10.1002/er.3955.
  18. Prabu S, Hsu SC, Lin JS, Wang HW. Rapid hydrogen generation from the reaction of aluminum powders and water using synthesized aluminum hydroxide catalysts. Topics in Catalysis. 2018;61:1633-40. doi: 10.1007/s11244-018-0970-x.
  19. Prabu S, Wang HW. Enhanced hydrogen generation from graphite-mixed aluminum hydroxides catalyzed Al/water reaction. Inter J Hydrogen Energy. 2020;45:33419-29. doi: 10.1016/j.ijhydene.2020.09.036.
  20. Prabu S, Wang HW. Hydrogen generation from the reaction of Al and H2O using a synthesized Al(OH)3 nanoparticle catalyst: The role of urea. Catalyst Sci Technol. 2021;11:4636-49 doi: 10.1039/D1CY00534K.
  21. Prabu S, Wang HW. Improved hydrogen generation from Al/water reaction using different synthesized Al(OH)3 catalyst crystalline phases. Inter J Ener Res. 2021;45:9518-29. doi: 10.1002/er.6478.
  22. Prabu S, Wang HW. Transition metal nanoparticles composite Al(OH)3 catalysts for hydrogen generation of Al/H2O system. J Taiwan Institute Chem Eng. 2023;145:104-771. doi: 10.1016/j.jtice.2023.104771.
  23. Chen YT, Huang, LY, Wang HW. Optimization of aluminum hydroxide catalyst for efficient hydrogen generation from aluminum-water reaction. International Journal of Hydrogen Energy. 2024;91:303-309. doi: 10.1016/j.ijhydene.2024.10.063.
  24. Gai WZ, Deng ZY, Enhanced hydrogen production from Al-water reaction: Strategies, performances, mechanisms and applications. Renewable Energy. 2024;226:120-397. doi: 10.1016/j.renene.2024.120397.
  25. Prabhsharan Kaur, Gaurav Verma, A critical assessment of aluminum-water reaction for on-site hydrogen-powered applications. Materials Today Energy. 2024;40:101-508. doi: 10.1016/j.mtener.2024.101508.
  26. Musicco N, Gelfi M, Iora P, Venturelli M, Artioli N, Montorsi L, Milani M. A review of hydrogen generation methods via aluminum and water reactions. International Journal of Thermofluids. 2025;27:101152. doi: 10.1016/j.ijft.2025.101152.


Comments


Publish with JBRES — Peer-reviewed, multidisciplinary Open Access with rapid review, DOI, and global visibility.
Double-Blind CrossRef DOI Discoverable